Wetting Alteration of Solid Surfaces by Crude Oils and Their Asphaltenes

Asphaltenes – Problems and Solutions in E&P of Brazilian Crude Oils

Maximum overheating and partial wetting of nonmelting solid surfaces.

Surfaces which do not exhibit surface melting below the melting point (nonmelting surfaces) have been recently observed to sustain a very large amount of overheating. We present a theory which identifies a maximum overheating temperature, and relates it to other thermodynamical properties of the surface, in particular to geometrical properties more readily accessible to experiment. These are th...

Wetting controls separation of inertial flows from solid surfaces.

We investigate the flow of liquids around solid surfaces in the inertial regime, a situation commonly encountered with the so-called "teapot effect", the annoying tendency for a liquid to trickle down the outside of a receptacle after pouring. We demonstrate that surface wettability is an unexpected key factor in controlling flow separation and trickling, the latter being completely suppressed ...

Analysis of Sulfur X-ray Absorption Near-edge Spectroscopy in Asphaltenes, Resins, and Maltenes of Two Different Crude Oils

Sulfur chemical structures present in crude oil products such as petroleum asphaltenes, resins, and maltenes obtained from two different oils have been determined using X-ray absorption nearedge structure (XANES) spectroscopy. Maltenes are pentane soluble portions, resins are pentane insoluble and heptane soluble portions, and asphaltenes are heptane insoluble portions of crude oil. The sulfur ...

Wetting theory for small droplets on textured solid surfaces

Conventional wetting theories on rough surfaces with Wenzel, Cassie-Baxter, and Penetrate modes suggest the possibility of tuning the contact angle by adjusting the surface texture. Despite decades of intensive study, there are still many experimental results that are not well understood because conventional wetting theory, which assumes an infinite droplet size, has been used to explain measur...